"....the duration of an
ordinary magnesium flash is about one-seventh of a second, and
although this is brief enough for ordinary portraiture, it is
too long when rapidly moving objects have to be photographed.
Much greater rapidity of combustion is obtained by mixing the
metal with certain substances rich in oxygen, such as potassium
chlorate. A larger quantity of magnesium can be burnt in this
way than is practicable in flash lamp or with gun-cotton.
It is very important to bear
in mind that these magnesium flash powders are really explosives,
and must be treated with all the respect due to such compounds.
Several fatal accidents have been caused in the past by carelessness
in this respect. With proper precautions, however, they can be
used with safety.
The points that must be specially
observed are as follows: - The ingredients must be kept separate,
and must only be mixed immediately before they are required for
use; any rubbing or powdering must be done whilst the ingredients
are separate; mixing should be done on a sheet of paper by means
of a knife, or by merely shaking the powders together, great
care being taken to avoid pressure or friction; no more should
be mixed than is required for use, and the mixed powder should
never be kept, much less carried about from place to place.
The powder is placed on a shallow
iron or lead tray, and is best ignited by touching it with burning
touch-paper-i.e. paper that has been soaked in a strong solution
of potassium nitrate, and dried. One end of a small strip of
touch-paper may be placed in the flash powder, and when the other
end is ignited it slowly burns down to the powder. For portraits,
however, the burning paper should be applied directly. A quantity
of powder containing 15grs of magnesium is amply sufficient for
an ordinary portrait. The powder should not be piled in a heap,
but should be arranged in a long narrow strip, as in the case
of the gun-cotton. If necessary, reflectors and screens must
be used as already described.
A very good mixture is: -
Potassium perchlorate 3 parts
Potassium chlorate 3 parts
Magnesium powder 4 parts
The chlorate and the perchlorate
may be very finely powdered and mixed together, but the chlorate
mixture and the magnesium must be kept separate until wanted
for use. 20 grains (2 parts) of magnesium is mixed on a sheet
of paper as already described, with 60 grains (3 parts) of the
mixture of perchlorate and chlorate (20 grains = 1.3grammes).
The duration of the flash is from one-eightieth to one-twentieth
of a second.
Whilst this powder may be safely
burnt in small quantities, the combustion is so violent that
it cannot be used in large quantities without danger. When a
large quantity of light is required, a mixture that burns more
slowly must be used. A mixture of magnesium powder with an equal
weight, or one and a half times its weight, of potassium nitrate,
prepared with all the precautions previously insisted on, may
be burnt in large quantity without detonation or explosion. When
a great space has to be illuminated, and large quantities of
powder are burnt, it becomes of the greatest importance to spread
it out in a moderately long strip, and not to pile it in a heap.
In such case it should be fired at the middle with a fuse of
touch-paper, the photographer standing at a safe distance.
When a broad flash is wanted,
paper which has been converted into what is practically gun-cotton
and thickly impregnated with magnesium is very convenient. It
is sold under the name of flash-bags.
|